It seems that the output has length only 1, so s[0] does not work.
 
 That's a solve idiosyncrasy :
 Each solution of a(n) (system of) equation(s) for n>1 variables is either a list of n equations (default) or a dictionary with n keys (when using solution_dict=True). solve returns a list of such solutions, i. e. either a list of n-long lists or a list of n-long dictionaries.
 However, when solving a(n) (system of) equation(s) for one variable and not using solution_dict=True, solve "simplifies" what should be a list of  1-long lists in a list of equations, each of them being a solution for this variable.
 This (disputable) simplification has been baked in Sage since Sage's early developers decoded to follow Maxima's conventions (dating from the early 1960's...) and is now a geological axiom. Complain fiercely...
 Workaround : use solution_dict=True, whose return values are more consistent (and usually easier to use, anyway...).
 HTH,